学術論文 | Organofluorine Chemistry Lab

2024年

154	"(1E)-1,2-Diaryldiazene Derivatives Containing a Donor-π-Acceptor-Type Tolane Skeleton as Smectic Liquid-Crystalline Dyes" Shigeyuki Yamada*, Keigo Yoshida, Yuto Eguchi, Mitsuo Hara, Motohiro Yasui, Tsutomu Konno Compounds 2024, 4(2), 288–300 [https://doi.org/10.3390/compounds4020015].
153	"Unsymmetrical and C₃-Symmetrical Partially Fluorinated Hexaarylbenzenes: Effect of Terminal Alkoxy Chain Length on Photophysical and Thermophysical Behavior" Yizhou Wang, Shigeyuki Yamada*, Motohiro Yasui, Tsutomu Konno Symmetry 2024, 16(3), 314 [https://doi.org/10.3390/sym16030314]
152	"A first example of a palladium-catalyzed allylic substitution reaction at a perfluoroalkylene-attached asymmetric carbon center with carbon, nitrogen, and oxygen nucleophiles" Machiko Kawazoe, Motohiro Yasui, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2024, 273, 110234 [https://doi.org/10.1016/j.jfluchem.2023.110234]
151	"Effects of fluorine atoms introduced into flexible chains or mesogenic structures on their liquid-crystalline and photoluminescence characteristics" Shigeyuki Yamada*, Keigo Yoshida, Mitsuo Hara, Tomohiro Agou, Motohiro Yasui, Tsutomu Konno J. Mol. Liq. 2024, 393, 123545 [https://doi.org/10.1016/j.molliq.2023.123545].

2023年

150	"Experimental and Theoretical Studies on Cobalt-Catalyzed Regioselective Hydrosilylation of Tetrafluorinated Cyclohexa-1,3-dienes" Kento Nagai, Suguru Morishitabara, Yuji Nishi, Chihiro Kajimoto, Motohiro Yasui, Takashi Yumura, Shigeyuki Yamada, Tsutomu Konno* Org. Lett. 2023, 25(38), 6975–6981 [https://doi.org/10.1021/acs.orglett.3c02453]
149	"Effects of Tetrafluorocyclohexa-1,3-Diene Ring Position on Photoluminescence and Liquid-Crytalline Properties of Tricyclic π-Conjugated Molecules" Haruka Ohsato, Shigeyuki Yamada, Motohiro Yasui, Tsutomu Konno* Crystals 2023, 13(8), 1208 [https://doi.org/10.1002/tcr.202300080]
148	“Diverse Synthetic Transformations using 4-bromo-3,3,4,4-tetrafluorobut-1-ene and its Applications in the Preparation of CF2CF2-Containing Sugars, Liquid Crystals, and Light-Emitting Materials” Haruka Ohsato, Kazuma Kawauchi, Shigeyuki Yamada, Tsutomu Konno* Chem. Rec. 2023, 23(9), e202300080 [https://doi.org/10.3390/cryst13081208].
147	“Development of Donor-π-Acceptor-Type Fluorinated Tolanes as Compact Condensed Phase Luminophores and Applications in Photoluminescent Liquid-Crystalline Molecules” Shigeyuki Yamada*, Tsutomu Konno Chem. Rec. 2023, 23(9), e202300094 [https://doi.org/10.1002/tcr.202300094].
146	“Donor-π-acceptor-type fluorinated tolane containing a semifluoroalkoxy chain as a condensed-phase luminophore” Shigeyuki Yamada*, Keigo Yoshida, Mitsuki Kataoka, Mitsuo Hara, Tsutomu Konno Molecules 2023, 28(6), 2764 [https://doi.org/10.3390/molecules28062764]
145	“Fluorinated Merophosphinine and Phosphinine Dyes: Synthesis and Evaluation of UV-Visible Light Absorption Properties” Shigeyuki Yamada*, Yusuke Takahashi, Tsutomu Konno Compounds 2023, 3(1), 153–168 [https://doi.org/10.3390/compounds3010013]. Selected as Editor's choice.
144	“Effects of peripheral ring fluorination on the photophysical properties of hexaarylbenzenes” Yizhou Wang, Shigeyuki Yamada*, Tsutomu Konno J. Fluorine Chem. 2023, 266, 110086 [https://doi.org/10.1016/j.jfluchem.2023.110086].
143	“Development of Hydrogen-Bonded Dimer-Type Photoluminescent Liquid Crystals of Fluorinated Tolanecarboxylic Acid” Shigeyuki Yamada*, Mitsuki Kataoka, Keigo Yoshida, Masakazu Nagata, Tomohiro Agou, Hiroki Fukumoto, Tsutomu Konno Crystals 2023, 13(1), 25 [https://doi.org/10.3390/cryst13010025].

2022年

142	“A novel terminal modification of perfluoropolyethers” Machiko Kawazoe, Masaki Ueda, Shigeyuki Yamada, Tsutomu Konno*, Shinya Takano, Takashi Nomura J. Fluorine Chem. 2022, 264, 110049 [https://doi.org/10.1016/j.jfluchem.2022.110049].
141	“Photophysical and thermophysical behavior of D-π-A-type fluorinated diphenylacetylenes bearing an alkoxy and an ethoxycarbonyl group at both longitudinal molecular terminals” Shigeyuki Yamada*, Mitsuki Kataoka, Keigo Yoshida, Masakazu Nagata, Tomohiro Agou, Hiroki Fukumoto, Tsutomu Konno Shinya Takano, Takashi Nomura J. Fluorine Chem. 2022, 261-262, 110032. (https://doi.org/10.1016/j.jflluchem.2022110032)
140	“Development of Yellow-to-Orange Photoluminescence Molecules Based on Alterations in the Donor Units of Fluorinated Tolanes” Shigeyuki Yamada*, Kazuki Kobayashi, Tsutomu Konno Molecules 2022, 27(18), 5782. (https://doi.org/10.3390/molecules27185782)
139	“Development of photoluminescent liquid-crystalline dimers bearing two fluorinated tolane-based luminous mesogen” Shigeyuki Yamada*, Eiji Uto, Tsuneaki Sakurai, Tsutomu Konno J. Mol. Liq. 2022, 363, 119844. (https://doi.org/10.1016/j.molliq.2022.119884)
138	“Development of termoresponsive near-ultraviolet photoluminescent liquid crystals using hexyloxy-terminated fluorinated tolane dimers connected with an alkylene spacer” Shigeyuki Yamada*, Eiji Uto, Tsuneaki Sakurai, Tsutomu Konno J. Mol. Liq. 2022, 362, 119755. (https://doi.org/10.1016/j.molliq.2022.119755)
137	“Aggregation-induced enhanced fluorescence by hydrogen bonding in π-conjugated tricarbocycles with a CF₂CF₂-containing cyclohexa-1,3-diene skeleton” Haruka Ohsato, Masato Morita, Shigeyuki Yamada, Tomohiro Agou, Hiroki Fukumoto, Tsutomu Konno* Mol. Syst. Des. Eng. 2022, 7(9), 1129–1137. (https://doi.org/10.1039/d2me00055e)
136	“Effect of fluorine atoms in flexible chains on the phase transitions and photophysical behavior of D-π-A-type 4-alkoxy-4'-cyanodiphenylacetylene” Shigeyuki Yamada*, Keigo Yoshida, Tsuneaki Sakurai, Mitsuo Hara, Tsutomu Konno Mol. Syst. Des. Eng. 2022, 7(7), 720–724. (https://doi.org/10.1039/d2me00057a)
135	“Fluorinated tolane-based fluorophores bearing a branched flexible unit with aggregation-induced emission enhancement characteristics” Shigeyuki Yamada*, Masaya Sato, Eiji Uto, Mitsuki Kataoka, Masato Morita, Tsutomu Konno New J. Chem. 2022, 46(7), 3392–3400. (https://doi.org/10.1039/d1nj05822c)
134	“Halogen atom effect of fluorinated tolanes on their luminescence characteristics” Masato Morita, Shigeyuki Yamada*, Tsutomu Konno New J. Chem. 2022, 46(10), 4562–4569. (https://doi.org/10.1039/d1nj05539a) 表紙絵に採用されました
133	“D-π-A-type fluorinated tolanes with a diphenylaminog group: Crystal polymorphism formation and photophysical behavior” Shigeyuki Yamada*, Kazuki Kobayashi, Masato Morita, Tsutomu Konno CrystEngComm 2022, 24(5), 936–941. (https://doi.org/10.1039/d1ce01671g)
132	“Synthesis and photoluminescence properties of fluorine-containing poly(phenylene vinylene) bearing hexafluorocyclopentene-fused phenanthrene unit” Hiroki Fukumoti, Kazuki Shiitsuka, Keisuke Yamada, Shigeyuki Yamada, Tsutomu Konno, Toshio Kubota, Tomohiro Agou Polym. Int. 2022, 71(1), 117–123. (https://doi.org/10.1002/pi.6291)
131	“Preparation and synthetic applications of novel tetrafluoroethylenating zinc reagent with a triple bond as its functional group” Chihiro Kajimoto, Takuto Kataoka, Shota Kageyama, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2022, 253, 109929. (https://doi.org/10.1016/j.jfluchem.2021.109929)

2021年

129	“Unsymmetrical Hexafluorocyclopentene-linked Twisted π-Conjugated Molecules as Dual-State Emissive Luminophores” Shigeyuki Yamada*, Akito Nishizawa, Kazuki Kobayashi, Keigo Yoshida, Masato Morita, Tomohiro Agou, Takaaki Hosoya, Hiroki Fukumoto, Tsutomu Konno Symmetry 2021, 13(10), 1885. (https://doi.org/10.3390/sym13101885)
128	“Effect of Fluoroalkyl-Substituent in Bistolane-Based Photoluminescent Liquid Crystals on Their Physical Behavior” Shigeyuki Yamada*, Yizhou Wang, Masato Morita, Qingzhi Zhang, David O’Hagan, Masakazu Nagata, Tomohiro Agou, Hiroki Fukumoto, Toshio Kubota, Mitsuo Hara, Tsutomu Konno Crystals 2021, 11(4), 450. (https://doi.org/10.3390/cryst11040450)
127	“Systematic Studies on the Effect of Fluorine Atoms in Fluorinated Tolanes on Their Photophysical Properties” Masato Morita, Shigeyuki Yamada*, Tsutomu Konno Molecules 2021, 26(8), 2274. (https://doi.org/10.3390/molecules26082274)
126	“Novel multi-functionalized fluorine-containing organometallics: Preparation and applications of tetrafluoroethylenated zinc reagent” Chihiro Kajimoto, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2021, 245, 109781. (https://doi.org/10.1016/j.jfluchem.2021.109781)
125	“Cobalt-Catalyzed C–H Activation/Annulation of Benzamides with Fluorine-Containing Alkynes: A Facile Route to 3- and 4-Fluoroalkylated Isoquinolinones” Tatsuya Kumon, Jianyan Wu, Miroku Shimada, Shigeyuki Yamada, Tomohiro Agou, Hiroki Fukumoto, Toshio Kubota, Gerald B. Hammond, Tsutomu Konno* J. Org. Chem. 2021, 86(7), 5183–5196. (https://doi.org/10.1021/acs.joc.1c00080)
124	“Practical Synthesis of a-Trifluoromethylated Pyridines Based on Regioselective Cobalt-Catalyzed [2+2+2] Cycloaddition using Trifluoromethylated Diynes with Nitriles” Tatsuya Kumon, Shigeyuki Yamada, Tomohiro Agou, Hiroki Fukumoto, Toshio Kubota, Gerald B. Hammond, Tsutomu Konno* Adv. Synth. Catl. 2021, 363(7) 1912–1922. (https://doi.org/10.1002/adsc.202001433)

2020年

123	“Regioselective cobalt(II)-catalyzed [2+3] cycloaddition reaction of fluoroalkylated alkynes with 2-formylphenylboronic acids: Easy access to 2-fluoroalkylated indenols” Tatsuya Kumon, Miroku Shimada, Jianyan Wu, Shigeyuki Yamada, Tsutomu Konno* Beilstein J. Org. Chem. 2020, 16, 2193–2200. (https://doi.org/10.3762/bjoc.16.184)
122	“Excited-state Dynamics of Room-Temperature Phosphorescent Organic Materials Based on Monobenzil and Bisbenzil Frameworks” Kaveendra Maduwantha, Shigeyuki Yamada, Kaveenga Rasika Koswattage, Tsutomu Konno, Takuya Hosokai Materials 2020, 13(17), 3904. (https://doi.org/10.3390/ma13173904)
121	“Fluorinated Tolane Dyads with Alkylene Linkage: Synthesis and Evaluation of Photophysical Characteristics” Shigeyuki Yamada*, Eiji Uto, Tomohiro Agou, Toshio Kubota, Tsutomu Konno Crystals 2020, 10(8), 711. (https://doi.org/10.3390/cryst10080711)
120	“Synthesis of Carbazole-Fused Azaborines via a Pd-Catalyzed C–H Actiation-Cyclization Reaction” Maakazu Nagata, Taku Oshiro, Yoshiyuki Mizuhata, Norihiro Tokitoh, Takaaki Hosoya, Shigeyuki Yamada, Tsutomu Konno, Hiroki Fukumoto,* Toshio Kubota,* Tomohiro Agou Bull. Chem. Soc. Jpn. 2021, 94(1), 21–23. (https://doi.org/10.1246/bcsj.20200129)
119	“Synthesis and Characterization of Photoluminescence Liquid Crystals Based on Flexible Chain-Bearing Pentafluorinated Bistolanes” Shigeyuki Yamada*, Masaya Sato, Tsutomu Konno Crystals 2020, 10(7), 607. (https://doi.org/10.3390/cryst10070603)
118	“Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules” Shigeyuki Yamada*, Takuya Higashida, Yizhou Wang, Masato Morita, Takuya Hosokai, Kaveendra Maduwantha, Kaveenga Rasika Koswattage, Tsutomu Konno Beilstein J. Org. Chem. 2020, 16, 1154–1162. (DOI: 10.3762/bjoc.16.102)
117	“Fluorine-Induced Emission Enhancement of Tolanes via Formation of Tight Molecular Aggregates” Masato Morita, Shigeyuki Yamada*, Tsutomu Konno New. J. Chem. 2020, 44, 6704–6708. (https://doi.org/10.1039/d0nj01268h)
116	“Visible-Transparent Aromatic Polymers Obtained by the Polycondensation of a Bis(trifluorovinyl)benzene with Bisphenols” Tomohiro Agou, Kazuto Yoshinari, Tomohiro Shirai, Shigeyuki Yamada, Tsutomu Konno, Yoshiyuki Mizuhata, Norihiro Tokitoh, Sana Yasuda, Takashi Yamazaki, Hiroki Fukumoto, Toshio Kubota Macromolecules 2020, 53(8), 2942–2949. (https://doi.org/10.1021/acs.macromol.0c00157)
115	“Facile Preparation of a,w-Diynes Bearing a Perfluoroalkylene Linker –(CF₂)_n- (n = 4, 6) and Their Application for Co- or Rh-Catalyzed [2+2+2] Cycloaddition Reactions Affording Aromatic Compounds with Perfluoroalkylene Units” Tomohiro Agou, Shogo Saruwatari, Tomohiro Shirai, Tatsuya Kumon, Shigeyuki Yamada, Tsutomu Konno, Yoshiyuki Mizuhata, Norihiro Tokitoh, Yoshihisa Sei, Hiroki Fukumoto, Toshio Kubota J. Fluorine Chem. 2020, 234, 109512. (https://doi.org/10.1016/j.jfluchem.2020.109512)
114	“Development of Light-Emitting Liquid-Crystalline Polymers with a Pentafluorinated Bistolane-Based Luminophore” Shigeyuki Yamada*, Akira Mitsuda, Kaoru Adachi, Mitsuo Hara, Tsutomu Konno New. J. Chem. 2020, 44, 5684–5691. (https://doi.org/10.1039/d0nj00659a)
113	“Synthesis and Application of Tetrafluoroethylene (CF₂CF₂)-Containing Acetylene Derivatives” Gen Egashira, Chihiro Kajimoto, Takuto Kataoka, Shigeyuki Yamada, Tsutomu Konno* Synthesis 2020, 52, 1947–1958. (https://doi.org/10.1055/s-0039-1691744)
112	“Helicenes Fused with Hexafluorocyclopentene (HFCP): Synthesis, Structure, and Properties” Tomohiro Agou, Masaki Kohara, Yuuki Tamura, Keisuke Yamada, Kazuki Shiitsuka, Takaaki Hosoya, Yoshiyuki Mizuhata, Norihiro Tokitoh, Yuki Hayashi, Yusuke Moronuki, Akihiro Ishii, Yusuke Tanaka, Atsuya Muranaka, Masanobu Uchiyama, Shigeyuki Yamada, Tsutomu Konno, Hiroki Fukumoto, Toshio Kubota Eur. J. Org. Chem. 2020, 1871–1880. (https://doi.org/10.1002/ejoc.202000152)
111	“1,2-Disubstituted 3,3,4,4,5,5-Hexafluorocyclopentenes as Bent Light-Emitting p-Conjugated Luminophores” Shigeyuki Yamada*, Akito Nishizawa, Tomohiro Agou, Takaaki Hosoya, Toshio Kubota, Tsutomu Konno Eur. J. Org. Chem. 2020, 870–877. (https://doi.org/10.1002/ejoc.201901794)

2019年

110	“Synthesis and Characterization of Bent Fluorine-Containing Donor-π-Acceptor Molecules as Intense Luminophores with Large Stokes Shift” Shigeyuki Yamada*, Akito Nishizawa, Masato Morita, Takuya Hosokai, Yusuke Okabayashi, Tomohiro Agou, Takaaki Hosoya, Toshio Kubota, Tsutomu Konno Org. Biomol. Chem. 2019, 17, 6911–6919. (https://doi.org/10.1039/c9ob01300h)
109	“Synthetic Utilization of Tetrafluoroethylene-Containing Silyl Reagent (CH₂=CHCF₂CF₂SiEt₃) in Cu(I)-Mediated Cross-Coupling Reaction with Various Iodoarenes” Ryosuke Yakushijin, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2019, 225, 35–43. (https://doi.org/10.1016/j.jfluchem.2019.06.001)
108	“First Practical Synthesis of 2- or 3-Fluoroalkylated Indenols via Cobalt-Catalyzed [2+3] Carbocyclization of Fluorine-Containing Alkynes and 2-Iodoaryl Ketones” Tatsuya Kumon, Kazuhiro Yoshida, Shigeyuki Yamada, Tomohiro Agou, Toshio Kubota, Tsutomu Konno* Tetrahedron 2019, 75, 3713–3721. (https://doi.org/10.1016/j.tet.2019.05.042)
107	“Luminescence Tuning of Fluorinated Bistolanes via Electronic or Aggregated-Structure Control” Masato Morita, Shigeyuki Yamada*, Tomohiro Agou, Toshio Kubota, Tsutomu Konno Appl. Sci. 2019, 9, 1905. (https://doi.org/10.3390/app9091905)
106	“2-Chloroalkoxy-Substituted Pentafluorinated Bistolanes as Novel Light-Emitting Liquid Crystals” Shigeyuki Yamada*, Kazuya Miyano, Tomohiro Agou, Toshio Kubota, Tsutomu Konno Crystals 2019, 9, 195. (https://doi.org/10.3990/cryst9040195)
105	“Novel V- and Y-Shaped Light-Emitting Liquid Crystals with Pentafluorinated Bistolane-Based Luminophores” Shigeyuki Yamada*, Tsuyoshi Tanaka, Takahiro Ichikawa, Tsutomu Konno ACS Omega 2019, 4, 3922–3932. (https://doi.org/10.1021/acsomega.8b03543)

2018年

104	“Stabilization of SF₅^– with Glyme-Coordinated Alkali Metal Cations” Kazuhiko Matsumoto, Yuki Haruki, Shunsuke Sawada, Shigeyuki Yamada, Tsutomu Konno, Rika Hagiwara Inorg. Chem. 2018, 57, 14882–14889. (https://doi.org/10.1021/acs.inorgchem.8b02655)
103	“A Straightforward Synthesisn of Polyfluorinated Furan Derivatives and Their Property” Tomohiro Agou, Seiya Nemoto, Shigeyuki Yamada, Tsutomu Konno, Yoshiyuki Mizuhata, Norihiro Tokitoh, Ryota Ebina, Akihiko Ishii, Takaaki Hosoya, Hiroki Fukumoto, Toshio Kubota Asian J. Org. Chem. 2018, 7, 2484–2489. (https://doi.org/10.1002/ajoc.201800454)
102	“Development of Novel Solid-State Light-Emitting Materials Based on Pentafluorinated Tolane Fluorophores” Shigeyuki Yamada*, Akira Mitsuda, Kazuya Miyano, Tsuyoshi Tanaka, Masato Morita, Tomohiro Agou, Toshio Kubota, Tsutomu Konno ACS Omega 2018, 3, 9105–9113. (https://doi.org/10.1021/acsomega.8b01490)
101	“Thermoresponsive Luminescent Properties of Polyfluorinated Bistolane-Type Light-Emitting Liquid Crystals” Shigeyuki Yamada*, Masato Morita, Tomohiro Agou, Toshio Kubota, Takahiro Ichikawa, Tsutomu Konno Org. Biomol. Chem. 2018, 16, 5609–5617. (https://doi.org/10.1039/c8ob01497c)
100	“Practical Tetrafluoroethylene Fragment Installation Through a Coupling Reaction of (1,1,2,2-Tetrafluorobut-3-en-1-yl)zinc Bromide with Various Electrophiles” Ken Tamamoto, Shigeyuki Yamada, Tsutomu Konno* Beilstein J. Org. Chem. 2018, 14, 2375–2383. (https://doi.org/10.3762/bjoc.14.213)
99	“Highly Regioselective Cobalt-Catalyzed [2+2+2] Cycloaddition of Fluorine-Containing Internal Alkynes to Construct Various Fluoroalkylated Benzene Derivatives” Tatsuya Kumon, Shigeyuki Yamada, Tomohiro Agou, Toshio Kubota, Tsutomu Konno* J. Fluorine Chem. 2018, 213, 11–17. (https://doi.org/10.1016/j.jfluchem.2018.06.004)
98	“An Asymmetric Tertiary Carbon Center with a Tetrafluoroethylene (-CF₂CF₂-) Fragment: Novel Construction Method and Application in a Chiral Liquid Crystalline Molecule” Keigo Yamashika, Suguru Morishitabara, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2018, 207, 24–37. (https://doi.org/10.1016/j.jfluchem.2017.12.013)
97	“Gram-Scale Preparation of Negative-Type Liquid Crystals with a CF₂CF₂-Carbocycle Unit via an Improved Short-Step Synthetic Protocol” Tatsuya Kumon, Shohei Hashishita, Takumi Kida, Shigeyuki Yamada, Takashi Ishihara, Tsutomu Konno* Beilstein J. Org. Chem. 2018, 14, 148–154. (https://doi.org/10.3762/bjoc.14.10)
96	“α-Substitution Effect of Fluorine Atoms in the Cobalt-Catalyzed Hydrosilylation of Fluorine-Containing Aromatic Ketones” Tatsuya Kumon, Siti Asiah Binti Mohd, Shigeyuki Yamada, Tsutomu Konno* J. Fluorine Chem. 2018, 206, 8–18. (https://doi.org/10.1016/j.jfluchem.2017.12.003)

2017年

95	“Rational Design and Synthesis of a Novel Laterally-Tetrafluorinated Tricyclic Mesogen with Large Negative Dielectric Anisotropy” Shigeyuki Yamada, Ken Tamamoto, Takumi Kida, Tomoyuki Asai, Takashi Ishihara, Tsutomu Konno* Org. Biomol. Chem. 2017, 15, 9442–9454. (https://doi.org/10.1039/c7ob02399e)
94	“Multi-Color Photoluminescence Induced by Electron-Density Distribution of Fluorinated Bistolane Derivatives” Shigeyuki Yamada*, Masato Morita, Tsutomu Konno J. Fluorine Chem. 2017, 202, 54–64. (https://doi.org/10.1016/j.jfluchem.2017.09.003)
93	“Fluorine-Containing Bistolanes as Light-Emitting Liquid Crystalline Molecules” [Selected as OBC HOT Articles 2017] Shigeyuki Yamada*, Kazuya Miyano, Tsutomu Konno, Tomohiro Agou, Toshio Kubota, Takuya Hosokai Org. Biomol. Chem. 2017, 15, 5949–5958. (https://doi.org/10.1039/c7ob01369h)
92	“New Entry for Fluorinated Carbocycles: Unprecedented 3,6-Disubstituted 1,1,2,2-Tetrafluorocyclohexane Derivatives” Shigeyuki Yamada, Shohei Hashishita, Hideaki Konishi, Yuji Nishi, Toshio Kubota, Tomoyuki Asai, Takashi Ishihara, Tsutomu Konno* J. Fluorine Chem. 2017, 200, 47–58. (https://doi.org/10.1016/j.jfluchem.2017.05.013)
91	“Design, Synthesis and Evaluation of New Fluorinated Liquid Crystals Bearing CF₂CF₂ Fragment with Negative Dielectric Anisotropy” [Highlighted in Synfacts 2017, 13, 0367] Shigeyuki Yamada, Shohei Hashishita, Tomoyuki Asai, Takashi Ishihara, Tsutomu Konno* Org. Biomol. Chem. 2017, 15, 1495–1509. (https://doi.org/10.1039/c6ob02431a)
90	“Stereochemically Defined Various Multi-Substituted Alkenes Bearing a Tetrafluoroethylene (-CF₂CF₂-) Fragment” Yukiho Sakaguchi, Shigeyuki Yamada, Tsutomu Konno*, Tomohiro Agou, Toshio Kubota J. Org. Chem. 2017, 82, 1618–1631. (https://doi.org/10.1021/acs.joc.6b02793)

2016年

89	“Radical Reactivity of α,β,β-Trifluoroacrylic Ester: Facile Approach to γ-Silyloxy-α,β,β-trifluorobutylic Acid Derivatives Involving Regioselective Nucleophilic Radical Addition Reaction” Ken Tamamoto, Shigeyuki Yamada, Masao Higashi, Tsutomu Konno, Takashi Ishihara* J. Fluorine Chem. 2016, 190, 23–30. (https://doi.org/10.1016/j.jfluchem.2016.08.011)
88	“Straightforward and Highly Stereoselective Synthesis of 3,3,4-Trifluoropyrrolidines Involving 1,3-Dipolar Cycloaddition with 2,3,3-Trifluoroacrylate” Shigeyuki Yamada, Masao Higashi, Tsutomu Konno, Takashi Ishihara* Eur. J. Org. Chem. 2016, 4561–4568. (https://doi.org/10.1002/ejoc.201600837)
87	“Concise Preparation of Fluorine-Containing Carbocycles Involving the Diels-Alder Reaction Using Fluorinated Alkene or Diene Derivatives” Shigeyuki Yamada, Kazunori Hondo, Tsutomu Konno*, Takashi Ishihara RSC Adv. 2016, 6, 28458–28469.(https://doi.org/10.1039/c6ra00569a)
86	“Highly Stereoselective Synthesis of Fluoroalkene Dipeptides via the Novel Cr(II)-Mediated Carbon-Fluorine Bond Cleavage/New Carbon-Carbon Bond Formation” Takashi Nihei, Yuji Nishi, Natsumi Ikeda, Saya Yokotani, Takashi Ishihara, Satoru Arimitsu, Tsutomu Konno* Synthesis 2016, 48, 865–881. (https://doi.org/10.1055/s-0035-1560390)

2015年

85	“Selective Synthesis of Fluoroalkyl-Containing Multisubstituted Benzenes Through Co-Mediated [2+2+2] Cycloaddition Reaction with Fluoroalkylated Alkynes” Yukiho Sakaguchi, Yoshitomo Nakazaki, Kazuki Moriyasu, Tsutomu Konno* J. Fluorine Chem. 2015, 179, 64–70. (https://doi.org/10.1016/j.jfluchem.2015.06.013)
84	“Copper(0)-Mediated Tetrafluoroethylenation of Various Aromatic Compounds” Yusuke Watanabe, Tsutomu Konno* J. Fluorine Chem. 2015, 174, 102–107. (https://doi.org/10.1016/j.jfluchem.2014.12.008)
83	“Highly Regio- and Stereoselective Hydrosilylation of b-Fluoroalkylated a,b-Unsaturated Ketones” Natsumi Ikeda, Tsutomu Konno* J. Fluorine Chem. 2015, 173, 69–71. (https://doi.org/10.1016/j.jfluchem.2015.02.010)
82	“An Efficient Approach to gem-Difluorocyclopropylstannanes via Highly Regio- and Stereoselective Hydrostannylation of gem-Difluorocyclopropenes and Their Unique Ring-opening Reaction to Afford β-Fluoroallylic Alcohols” Takashi Nihei, Tomoko Hoshino, Tsutomu Konno* Org. Biomol. Chem. 2015, 13, 3721–3731. (https://doi.org/10.1039/c5ob00046g)

2014年

81	“Unusual Reaction Behavior of gem-Difluorocyclopropane Derivatives: Stereoselective Synthesis of β-Monofluoroallylic Alcohols, Ethers, Esters, and Amides” Takashi Nihei, Tomoko Hoshino, Tsutomu Konno* Org. Lett. 2014, 16, 4170–4173. (https://doi.org/10.1021/ol5018596)
80	“Highly Regioselective S_N2’ Reaction of β-Fluoroallylic Phosphates with Oganocopper Reagents and Its Application to the Synthesis of Fluorine-Containing Carbocycles” Takashi Nihei, Yusuke Kubo, Takashi Ishihara, Tsutomu Konno* J. Fluorine Chem. 2014, 167, 110–121。 (https://doi.org/10.1016/j.jfluchem.2014.06.012)
79	“Stereoselective Synthesis of CF₃-Substituted trans- and cis-Endiynes via Carbocupration or Hydrostannation Reactions of CF₃-Containing Diyne” Tsutomu Konno*, Misato Kishi, Takashi Ishihara, Shigeyuki Yamada Tetrahedron 2014, 70, 2455–2463. (https://doi.org/10.1016/j.tet.2014.02.015)
78	“A Remarkable Regiocontrol in the Palladium-Catalyzed Silylstannylation of Fluoroalkylated Alkynes – Highly Regio- and Stereoselective Synthesis of Multi-Substituted Fluorine-Containing Alkenes” Tsutomu Konno*, Ryoko Kinugawa, Takashi Ishihara, Shigeyuki Yamada Org. Biomol. Chem. 2014, 12, 1611–1617. (https://doi.org/10.1039/c3ob41903g)
77	“Stereocontrolled Generation of Nucleophilic (Z)- or (E)-α-Fluoroalkenylchromium Reagents via Carbon-Fluorine Bond Activation: Highly Stereoselective Synthesis of (E)- or (Z)-β-Fluoroallylic Alcohols” Takashi Nihei, Saya Yokotani, Takashi Ishihara, Tsutomu Konno* Chem. Commun. 2014, 50, 1543–1545. (https://doi.org/10.1039/c3cc47219a)

2013年

76	“Highly Stereoselective Approach to 3-Fluoroalkylated (E)-Hex-3-ene-1,5-diyne Derivatives via an Addition-Elimination Reaction” Tsutomu Konno*, Misato Kishi, Takashi Ishihara, Shigeyuki Yamada J. Fluorine Chem. 2013, 156, 144–151. (https://doi.org/10.1016/j.jfluchem.2013.09.010)
75	“Short Synthetic Preparation of Enantiomerically Pure Tetrafluoroethylenated Sugar Derivatives” Tsutomu Konno*, Tomoko Hoshino, Takumi Kida, Shinya Takano, Takashi Ishihara J. Fluorine Chem. 2013, 152, 106–113. (https://doi.org/10.1016/j.jfluchem.2013.02.013)
74	“Application of Tertiary Amines Synthesized by Catalytic Dehydrogenation of Enamines as Nucleophiles C2 Synthons for 1,4-Conjugate Addition with Fluoroalkylated Olefins” Atsunori Morigaki, Mio Kawamura, Satoru Arimitsu, Takashi Ishihara, Tsutomu Konno* Asian J. Org. Chem. 2013, 2, 239–243. (https://doi.org/10.1002/ajoc.201300007)
73	“Fluorine-Copper Exchange Reaction of α,β,γ,γ,γ-Pentafluorocrotonates with Organocuprates: Generation and Cross-Coupling Reactions of β-Metallated α,γ,γ,γ-Tetrafluorocrotonates” Shigeyuki Yamada, Toshio Takahashi, Tsutomu Konno, Takashi Ishihara* J. Fluorine Chem. 2013, 149, 95–103. (https://doi.org/10.1016/j.jfluchem.2013.01.031)
72	“Unusual Annulation Reaction of Electron-Deficient Alkenes with Enamines: An Easy Access to Stereocontrolled 4-Fluoroalkylated 3,4-Dihydro-2H-pyrans” Atsunori Morigaki, Kazuki Tsukade Satoru Arimitsu, Tsutomu Konno* Tetrahedron 2013, 69, 1521–1525. (https://doi.org/10.1016/j.tet.2012.12.012)
71	“Rhodium(I)-Catalyzed 1,4-Conjugate Acylation Toward β-Fluoroalkylated Electron-Deficient Alkenes: A New Entry to a Construction of a Tertiary Carbon Center Possessing a Fluoroalkyl Group” Atsunori Morigaki, Tomoo Tanaka, Tomotsugu Miyabe, Takashi Ishihara, Tsutomu Konno* Org. Biomol. Chem. 2013, 11, 586–595. (https://doi.org/10.1039/c2ob26708j)
70	“The First Practical Additive-Free 1,4-Conjugated Alkylation of Fluoroalkylated Electron-Deficient Olefins with Various Organozinc Reagents” Atsunori Morigaki, Tomotsugu, Miyabe, Kazuki Tsukade, Satoru Arimitsu, Takashi Ishihara, Tsutomu Konno* Synthesis 2013, 45, 101–105. (https://doi.org/10.1055/s-0032-1317707)

2012年

69	“Highly Stereocontrolled Synthesis of trans-Enediynes via Carbocupration of Fluoroalkylated Diynes” Tsutomu Konno*, Misato Kishi, Takashi Ishihara Beilstein J. Org. Chem. 2012, 8, 2207–2213. (https://doi.org/10.3762/bjoc.8.249)
68	“A Novel Synthesis of Fluorine-Containing Cyclopentenones via Pauson-Khand Reaction” Tsutomu Konno*, Takumi Kida, Akinori Tani, Takashi Ishihara J. Fluorine Chem. 2012, 144, 147–156. (https://doi.org/10.1016/j.jfluchem.2012.08.006)
67	“A New Entry to The Construction of a Quaternary Carbon Center Having a Fluorine Atom – S_N2’ Reaction of γ-Fluoroallylic Alcohol Derivatives with Various Organocuprates” Tsutomu Konno*, Atsushi Ikemoto, Takashi Ishihara Org. Biomol. Chem. 2012, 10, 8154–8163. (https://doi.org/10.1039/c2ob25718a)
66	“A New Entry for The Oxidation of Fluoroalkyl-Substituted Methanol Derivatives: Scope and Limitation of The Organoiodine(V) Reagent-Catalyzed Oxidation” Yusuke Tanaka, Takashi Ishihara, Tsutomu Konno* J. Fluorine Chem. 2012, 137, 99–104. (https://doi.org/10.1016/j.jfluchem.2012.03.002)

2011年

65	“Easy Access to CF₂-Containing Molecules Based on The Reaction of 2,2,3,3-Tetrafluorooxetane with Various Nucleophiles” Shigeyuki Yamada, Masahiro Kato, Yudai Komori, Tsutomu Konno, Takashi Ishihara* Org. Biomol. Chem. 2011, 9, 5493–5502. (https://doi.org/10.1039/c1ob05545c)
64	“Novel Introduction of a Tetrafluoroethylene (-CF₂CF₂-) Unit into Organic Molecules” Tsutomu Konno*, Shinya Takano, Yoshikazu Takahashi, Hideaki Konishi, Yusuke Tanaka, Takashi Ishihara Synthesis 2011, 33–44. (https://doi.org/10.1055/s-0030-1258330)

“Easy Access to CF₂-Containing Molecules Based on The Reaction of 2,2,3,3-Tetrafluorooxetane with Various Nucleophiles”

Shigeyuki Yamada, Masahiro Kato, Yudai Komori, Tsutomu Konno, Takashi Ishihara*
Org. Biomol. Chem. 2011, 9, 5493–5502. (https://doi.org/10.1039/c1ob05545c)

“Novel Introduction of a Tetrafluoroethylene (-CF₂CF₂-) Unit into Organic Molecules”

Tsutomu Konno*, Shinya Takano, Yoshikazu Takahashi, Hideaki Konishi, Yusuke Tanaka, Takashi Ishihara
Synthesis 2011, 33–44. (https://doi.org/10.1055/s-0030-1258330)

2010年

63	“Dispersion Behavior of Multi-walled Carbon Nanotubes with Pyrene-Containing Linear and Graft Polymers as Non-covalent Surface Modifiers” Maiko Matsuoka, Minoru Yamamoto, Kaoru Adachi, Yasuhisa Tsukahara, Tsutomu Konno Design Monom. Polym. 2010, 13, 387–397. (https://doi.org/10.1163/138577210X509615)
62	“An Effective Preparation of Sulfenyl- or Sulfonyl-Substituted Fluorinated Alkenes and Their Stereoselective Addition-Elimination Reactions with Organocuprates” Shigeyuki Yamada, Kanoko Shimoji, Toshio Takahashi, Tsutomu Konno, Takashi Ishihara* Chem. Asian J. 2010, 5, 1846–1853. (https://doi.org/10.1002/asia.20100022)
61	“Rhodium-Catalyzed [2+2+2] Cycloaddition of Various Fluorine-Containing Alkynes – Novel Synthesis of Multi-Substituted Fluoroalkylated Aromatic Compounds” Tsutomu Konno*, Kazuki Moriyasu, Ryoko Kinugawa, Takashi Ishihara Org. Biomol. Chem. 2010, 8, 1718–1724. (https://doi.org/10.1039/b926192c)

“Dispersion Behavior of Multi-walled Carbon Nanotubes with Pyrene-Containing Linear and Graft Polymers as Non-covalent Surface Modifiers”

Maiko Matsuoka, Minoru Yamamoto, Kaoru Adachi, Yasuhisa Tsukahara, Tsutomu Konno
Design Monom. Polym. 2010, 13, 387–397. (https://doi.org/10.1163/138577210X509615)

“An Effective Preparation of Sulfenyl- or Sulfonyl-Substituted Fluorinated Alkenes and Their Stereoselective Addition-Elimination Reactions with Organocuprates”

Shigeyuki Yamada, Kanoko Shimoji, Toshio Takahashi, Tsutomu Konno, Takashi Ishihara*
Chem. Asian J. 2010, 5, 1846–1853. (https://doi.org/10.1002/asia.20100022)

“Rhodium-Catalyzed [2+2+2] Cycloaddition of Various Fluorine-Containing Alkynes – Novel Synthesis of Multi-Substituted Fluoroalkylated Aromatic Compounds”

Tsutomu Konno*, Kazuki Moriyasu, Ryoko Kinugawa, Takashi Ishihara
Org. Biomol. Chem. 2010, 8, 1718–1724. (https://doi.org/10.1039/b926192c)

2009年

60	“An Efficient Protocol for the Stereoselective Construction of Multisubstituted Fluorine-Containing Alkenes. A Palladium-Catalyzed Bisstannylation of Fluorinated Internal Alkynes” Tsutomu Konno*, Ryoko Kinugawa, Atsunori Morigaki, Takashi Ishihara J. Org. Chem. 2009, 74, 8456–8459. (https://doi.org/10.1021/jo9017028)
59	“Unexpected High RegioControl in Heck Reaction of Fluorine-Containing Electron-Deficient Olefins – Highly Regio- and Stereoselective Synthesis of β-Fluoroalkyl-α,β-Unsaturated Ketones” Tsutomu Konno*, Shigeyuki Yamada, Akinori Tani, Masataka Nishida, Tomotsugu Miyabe, Takashi Ishihara J. Fluorine Chem. 2009, 130, 913–921. (https://doi.org/10.1016/j.jfluchem.2009.07.002)
58	“A Remarkable Access to γ-Fluoroalkylated Propargylamine Derivatives or Fluoroalkylated Dihydroisoxazoles via the Reaction of Fluoroalkylated Acetylides with Various Nitrones” Tsutomu Konno*, Kazuki Moriyasu, Takashi Ishihara Synthesis 2009, 1087–1094. (https://doi.org/10.1055/s-0028-1087988)
57	“Remarkable Access to Fluoroalkylated Trisubstituted Alkenes via Highly Stereoselective Cobalt-Catalyzed Hydrosilylation Reaction of Fluoroalkylated Alkynes” Tsutomu Konno*, Ken-ichi Taku, Shigeyuki Yamada, Kazuki Moriyasu, Takashi Ishihara Org. Biomol. Chem. 2009, 7, 1167–1170. (https://doi.org/10.1039/b819476a)

2008年

56	“Preparation of Perfluorocyclopentenylmetal Species and Their Cross-Coupling Reaction with Electrophiles – Remarkable Accesses to Versatile Perfluorocyclopentene Derivatoves” Shigeyuki Yamada, Emi Ishii, Tsutomu Konno, Takashi Ishihara* Tetrahedron 2008, 64, 4215–4223. (https://doi.org/10.1016/j.tet.2008.02.089)
55	“A First High Enantiocontrol of an Asymmetric Tertiary Carbon Center Attached with a Fluoroalkyl Group via Rh(I)-Catalyzed Conjugate Addition Reaction” Tsutomu Konno*, Tomoo Tanaka, Tomotsugu Miyabe, Atsunori Morigaki, Takashi Ishihara Tetrahedron Lett. 2008, 49, 2106–2110. (https://doi.org/10.1016/j.tetlet.2008.01.122)
54	“Convenient and Efficient Access to Fluoroalkylated Vinylphosphonates via Highly Regio- and Stereoselective Hydrometalation or Carbometalation Reactions of Fluorine-Containing Alkynylphosphonates” Tsutomu Konno*, Atsunori Morigaki, Kazuo Ninomiya, Tomotsugu Miyabe, Takashi Ishihara Synthesis 2008, 564–572. (https://doi.org/10.1055/s-2008-1032143)
53	“Preparation and Addition-Elimination Reactions of Benzyl α,β,β-Trifluoroacrylate. A New Stereoselective Approach to (Z)-β-Substituted α,β-Difluoroacrylates” Shigeyuki Yamada, Mayumi Noma, Kazunori Hondo, Tsutomu Konno, Takashi Ishihara＊ J. Org. Chem. 2008, 73, 522–528. (https://doi.org/10.1021/jo701975y)

2007年

52	“A Novel Fluorine-Metal Exchange Reaction of Pentafluorocrotonate with Organocuprate. Generation of β-Metallated Tetrafluorocrotonate and Its Cross-Coupling Reaction” Shigeyuki Yamada, Toshio Takahashi, Tsutomu Konno, Takashi Ishihara* Chem. Commun. 2007, 3679–3681. (https://doi.org/10.1039/b705408d)
51	“A New Access to 3-Halo-3,3-difluoropropanoic Acid Derivatives via Fluorine-Halogen Exchange Reaction of Silyl Enolates of 3,3,3-Trifluoropropanoic Acid Derivatives” Taichi Shimada, Tsutomu Konno, Takashi Ishihara* Chem. Lett. 2007, 36, 636–637. (https://doi.org/10.1246/cl.2007.636)
50	“Reaction of Perfluorocyclopentene with Various Carbon Nucleophiles – Heteroaromatic Lithium Reagents, Enolate and Phophonium Ylide” Shigeyuki Yamada, Emi Ishii, Tsutomu Konno, Takashi Ishihara* Org. Biomol. Chem. 2007, 5, 1442–1449. (https://doi.org/10.1039/b701702b)

“A Novel Fluorine-Metal Exchange Reaction of Pentafluorocrotonate with Organocuprate. Generation of β-Metallated Tetrafluorocrotonate and Its Cross-Coupling Reaction”

Shigeyuki Yamada, Toshio Takahashi, Tsutomu Konno, Takashi Ishihara*
Chem. Commun. 2007, 3679–3681. (https://doi.org/10.1039/b705408d)

“A New Access to 3-Halo-3,3-difluoropropanoic Acid Derivatives via Fluorine-Halogen Exchange Reaction of Silyl Enolates of 3,3,3-Trifluoropropanoic Acid Derivatives”

Taichi Shimada, Tsutomu Konno, Takashi Ishihara*
Chem. Lett. 2007, 36, 636–637.
(https://doi.org/10.1246/cl.2007.636)

“Reaction of Perfluorocyclopentene with Various Carbon Nucleophiles – Heteroaromatic Lithium Reagents, Enolate and Phophonium Ylide”

Shigeyuki Yamada, Emi Ishii, Tsutomu Konno, Takashi Ishihara*
Org. Biomol. Chem. 2007, 5, 1442–1449. (https://doi.org/10.1039/b701702b)

2006年

49	“A Novel Synthesis of Trifluoromethylated Multi-Substituted Alkenes via Regio and Stereoselective Heck Reaction of (E)-4,4,4-Trifluoro-1-phenyl-2-buten-1-one” Tsutomu Konno*, Shigeyuki Yamada, Akinori Tani, Tomotsugu Miyabe, Takashi Ishihara Synlett 2006, 3025–3028. (https://doi.org/10.1055/s-2006-951496)
48	“Synthetic Application of Fluorinated Vinamidinium Salts: Synthesis of Fluorinated 1,3-Butadienylphosphonates by The Reaction with Horner-Wadsworth-Emmons Reagents” Satoru Arimitsu, Tsutomu Konno, John T. Gupton, Takashi Ishihara, Hiroki Yamanaka* J. Fluorine Chem. 2006, 127, 1235–1241. (https://doi.org/10.1016/j.jfluchem.2006.07.001)
47	“First Highly Stereoselective Synthesis of anti-α-Trifluoromethyl-β-amino Acid Derivatives” Taichi Shimada, Masamitsu Yoshioka, Tsutomu Konno, Takashi Ishihara* Chem. Commun. 2006, 3628–3630. (https://doi.org/10.1039/b603882d)
46	“Highly Stereoselective One-pot Synthesis of Tetrasubstituted Alkenes via Carbopalladation Reaction of Fluorine-Containing Acetylene Derivatives” Tsutomu Konno*, Ken-ichi Taku, Takashi Ishihara J. Fluorine Chem. 2006, 127, 966–972. (https://doi.org/10.1016/j.jfluchem.2006.04.012)
45	“A Novel Synthetic Approach to Fluorine-Containing Acetylene Compounds Based on Nicolas Reaction” Tsutomu Konno*, Go Nagai, Takashi Ishihara J. Fluorine Chem. 2006, 127, 510–518. (https://doi.org/10.1016/j.jfluchem.2005.11.009)
44	“Palladium-Catalyzed Regio- and Stereoselective Formate Reduction of Fluorine-Containing Allylic Mesylates: A New Entry for the Construction of a Tertiary Carbon Attached with a Fluoroalkyl Group” Tsutomu Konno*, Tsuyoshi Takehana, Makoto Mishima, Takashi Ishihara J. Org. Chem. 2006, 71, 3545–3550. (https://doi.org/10.1021/jo0602120)
43	“Preparation of Trifluoromethylated Ynamines and Their Reactions with Some Electrophilic Reagents” Takashi Ishihara*, Toshiya Mantani, Tsutomu Konno, Hiroki Yamanaka Tetrahedron 2006, 62, 3783–3793. (https://doi.org/10.1016/j.tet.2005.11.086)
42	“Highly Stereoselective TiCl₄-Catalyzed Evans-Aldol and Et₃Al-Mediated Reformatsky Reactions. Efficient Accesses to Optically Active syn or anti-α-Trifluoromethyl-β-hydroxy Carboxylic Acid Derivatives” Taichi Shimada, Masamitsu Yoshioka, Tsutomu Konno, Takashi Ishihara* Org. Lett. 2006, 8, 1129–1131. (https://doi.org/10.1021/ol0531435)
41	“Novel Synthesis of (Z)-Difluoroacrylates via a Highly Stereoselective Addition-Elimination Reaction” Shigeyuki Yamada, Mayumi Noma, Tsutomu Konno, Takashi Ishihara*, Hiroki Yamanaka Org. Lett. 2006, 8, 843–845. (https://doi.org/10.1021/ol052897g)
40	“Highly Regio- and Stereoselective Hydrometallation Reactions of Fluorine-Containing Internal Alkynes: Novel Approaches to Fluoroalkylated Alkenes” Tsutomu Konno*, Jungha Chae, Tomoo Tanaka, Takashi Ishihara, Hiroki Yamanaka J. Fluorine Chem. 2006, 127, 36–43. (https://doi.org/10.1016/j.jfluchem.2005.09.015)

2005年

39	“A Novel Synthesis of Fluorine-Containing Quaternary Amino Acid Derivatives via Palladium-Catalyzed Allylation Reaction” Tsutomu Konno*, Masashi Kanda, Takashi Ishihara, Hiroki Yamanaka J. Fluorine Chem. 2005, 126, 1517–1523. (https://doi.org/10.1016/j.jfluchem.2005.08.013)
38	“Regioselective One-Step Synthesis of 4-Fluoroalkylated Isoquinolins via Carbopalladation Reaction of Fluorine-Containing Alkynes” Tsutomu Konno*, Jungha Chae, Tomotsugu Miyabe, Takashi Ishihara J. Org. Chem. 2005, 70, 10172–10174. (https://doi.org/10.1021/jo051700v)
37	“Highly Regio- and Stereoselective Carbometallation Reaction of Fluorine-Containing Internal Acetylenes with Organocopper Reagents” Tsutomu Konno*, Takeshi Daitoh, Atsushi Noiri, Jungha Chae, Takashi Ishihara, Hiroki Yamanaka Tetrahedron 2005, 61, 9391–9404. (https://doi.org/10.1016/j.tet.2005.07.022)
36	“Reaction of Octafluorocyclopentene with Various Carbon Nucleophiles” Shigeyuki Yamada, Tsutomu Konno, Takashi Ishihara* J. Fluorine Chem. 2005, 126, 125–133. (https://doi.org/10.1016/j.fluchem.2004.10.047)

2004年

35	“A First Regioselective Synthesis of 3-Fluoroalkylated Benzofurans via Palladium-Catalyzed Annulation of Fluorine-Containing Internal Alkynes with Variously Substituted 2-Iodophenol” Tsutomu Konno*, Jungha Chae, Takashi Ishihara, Hiroki Yamanaka Tetrahedron 2004, 60, 11695–11700. (https://doi.org/10.1016/j.tet.2004.10.005)
34	“A Facile Regiocontrol in the Palladium-Catalyzed Annulation of Fluorine-Containing Internal Alkynes with Variously Substituted 2-Iodoanilines: A New Regioselective Synthesis of 2- or 3-Fluoroalkylated Indole Derivatives” Tsutomu Konno*, Jungha Chae, Takashi Ishihara, Hiroki Yamanaka J. Org. Chem. 2004, 69, 8258–8265. (https://doi.org/10.1021/jo048872x)
33	“Highly Diastereoselective Reductive Coupling of 2-Bromo-2,3,3,3-tetrafluoropropanamide with Aldehydes Promoted by Triphenylphosphine-Titanium(IV) Isopropoxide. An Efficient Route to the Synthesis of erythro-α-Fluoro-α-(trifluoromethyl)-β-hydroxy Amides” Kei Sato, Takashi Sekiguchi, Takashi Ishihara*, Tsutomu Konno, Hiroki Yamanaka J. Org. Chem. 2004, 69, 5041–5047 (https://doi.org/10.1021/jo0358729).
32	“Zinc-Mediated Coupling Reaction of 2-Bromo-2,3,3,3-tetrafluoropropanoate with Various Chiral Imines. Simple and Effective Access to Optically Active α-Fluoro-α-(trifluoromethyl)-β-amino Esters” Takashi Sekiguchi, Kei Sato, Takashi Ishihara* Chem. Lett. 2004, 33, 666–667. (https://doi.org/10.1246/cl.2004.666)
31	“A Facile Synthesis of Various Fluorine-Containing Indole Derivatives via Palladium-Catalyzed Annulation of Internal Alkynes” Jungha Chae, Tsutomu Konno*, Takashi Ishihara, Hiroki Yamanaka Chem. Lett. 2004, 33, 314–315. (https://doi.org/10.1246/cl.2004.314)
30	“A Highly Regio- and Stereoselective Carbocupration of Fluoroalkylated Internal Alkynes: A Short Total Synthesis of the Antiestrogenic Drug Panomifene” Tsutomu Konno*, Takeshi Daitoh, Atsushi Noiri, Jungha Chae, Takashi Ishihara, Hiroki Yamanaka Org. Lett. 2004, 6, 933–936. (https://doi.org/10.1021/ol036440n)
29	“Highly Regio- and Stereoselective Carbostannylation Reaction of Fluorine-Containing Internal Acetylenes with Allylstannanes” Tsutomu Konno*, Tsuyoshi Takehana, Jungha Chae, Takashi Ishihara, Hiroki Yamanaka J. Org. Chem. 2004, 69, 2188–2190. (https://doi.org/10.1021/jo030272v)
28	“A Sequential Highly Stereoselective Hydroboration and Suzuki-Miyaura Cross-Coupling Reaction of Fluoroalkylated Internal Acetylenes: A Practical One-pot Synthesis of Fluoroalkylated Trisubstituted Alkenes” Tsutomu Konno*, Jungha Chae, Tomoo Tanaka, Takashi Ishihara, Hiroki Yamanaka Chem. Commun. 2004, 690–691. (https://doi.org/10.1039/b316065c)
27	“Highly Stereoselective Aldol-type Reaction of 2-Bromo-2,3,3,3-tetrafluoropropanamide with Aldehydes Leading to Erythro-α-Fluoro-α-(trifluoromethyl)-β-hydroxy Amides” Kei Sato, Takashi Sekiguchi, Takashi Ishihara*, Tsutomu Konno, Hiroki Yamanaka Chem. Lett. 2004, 33, 154–155. (https://doi.org/10.1246/cl.2004.154)
26	“The Fluorine-Containing π-Allylmetal Complex. The Transition Metal-Catalyzed Allylic Substitution Reaction of Fluorinated Allyl Mesylates with Various Carbon Nucleophiles” Tsutomu Konno*, Tsuyoshi Takehana, Takashi Ishihara, Hiroki Yamanaka Org. Biomol. Chem. 2004, 2, 93–98. (https://doi.org/10.1039/b310950j)

2003年

25	“Facile Syntheses of Various Per- or Polyfluoroalkylated Internal Acetylene Derivatives” Tsutomu Konno*, Jungha Chae, Masashi Kanda, Go Nagai, Kazushige Tamura, Takashi Ishihara, Hiroki Yamanaka Tetrahedron 2003, 59, 7571–7580. (https://doi.org/10.1016/s0040-4020(03)01199-2).
24	“A Highly Regio- and Stereoselective Hydrostannation Reaction of Various Fluorine-Containing Internal Acetylene Derivatives” Jungha Chae, Tsutomu Konno*, Masashi Kanda, Takashi Ishihara, Hiroki Yamanaka J. Fluorine Chem. 2003, 120, 185–193. (https://doi.org/10.1016/s0022-1139(-02)00328-7)
23	“Reaction of b-Trifluoroethoxy Vinamidinium Salts with Carbon Nucleophiles” Koichiro Kase, Mitsuhiko Katayama, Tsutomu Konno, Takashi Ishihara, Hiroki Yamanaka* J. Fluorine Chem. 2003, 120, 33–39. (https://doi.org/10.1016/s0022-1139(02)00281-6)

“Facile Syntheses of Various Per- or Polyfluoroalkylated Internal Acetylene Derivatives”

Tsutomu Konno*, Jungha Chae, Masashi Kanda, Go Nagai, Kazushige Tamura, Takashi Ishihara, Hiroki Yamanaka
Tetrahedron 2003, 59, 7571–7580. (https://doi.org/10.1016/s0040-4020(03)01199-2).

“A Highly Regio- and Stereoselective Hydrostannation Reaction of Various Fluorine-Containing Internal Acetylene Derivatives”

Jungha Chae, Tsutomu Konno*, Masashi Kanda, Takashi Ishihara, Hiroki Yamanaka
J. Fluorine Chem. 2003, 120, 185–193. (https://doi.org/10.1016/s0022-1139(-02)00328-7)

“Reaction of b-Trifluoroethoxy Vinamidinium Salts with Carbon Nucleophiles”

Koichiro Kase, Mitsuhiko Katayama, Tsutomu Konno, Takashi Ishihara, Hiroki Yamanaka*
J. Fluorine Chem. 2003, 120, 33–39. (https://doi.org/10.1016/s0022-1139(02)00281-6)

2002年

22	“Fluorine-Containing Allenylpalladium Complexes. Synthesis of Optically Active Fluoroalkylated Allenes and Furan Derivatives” Tsutomu Konno*, Mitsuru Tanikawa, Takashi Ishihara, Hiroki Yamanaka Collect. Czech. Chem. Commun. 2002, 67, 1421–1435. (https://doi.org/10.1135/cccc200214121)
21	“Stereoselective Synthesis of 3-Fluorotetrahydrofuran-3-carboxylate Derivatives via the Intramolecular Cyclization Reaction of erythro- and threo-α-Allylated α-Fluoro-β-hydroxy Esters” Kazuhide Mima, Kei Sato, Takashi Ishihara*, Tsutomu Konno, Hiroki Yamanaka J. Fluorine Chem. 2002, 115, 55–65. (https://doi.org/10.1016/s0022-1139(02)00005-2)
20	“Highly Efficient and Stereoselective Route to threo- and erythro-α-Allylated α-Fluoro-β-hydroxy Esters via Radical Allylation Reaction” Takashi Ishihara*, Kazuhide Mima, Tsutomu Konno, Hiroki Yamanaka Tetrahedron Lett. 2002, 43, 3493–3497. (https://doi.org/10.1016/s0040-4039(02)00608-1)
19	“An Efficient Method for the Diastereoselective Synthesis of α-Fluoro-β-hydroxy Esters Based on the Radical Reduction of α-Bromo-α-fluoro-β-hydroxy Esters” Kazuhide Mima, Takashi Ishihara*, Saki Kuwahata, Tsutomu Konno, Hiroki Yamanaka Tetrahedron 2002, 58, 2369–2376. (https://doi.org/10.1016/s0040-4020(02)00119-9)
18	“Concise Synthesis of Nonracemic γ-Fluoroalkylated Allylic Alcohols and Amines via an Enantiospecific Palladium-Catalyzed Allylic Substitution Reaction” Tsutomu Konno*, Kensuke Nagata, Takashi Ishihara, Hiroki Yamanaka J. Org. Chem. 2002, 67, 1768–1775. (https://doi.org/10.1021/jo011013d)
17	“Highly Stereoselective Radical Reduction of α-Bromo-α-fluoro-β-hydroxy Esters with Tributyltin Hydride Leading to threo-α-Fluoro-β-hydroxy Esters” Kazuhide Mima, Takashi Ishihara*, Saki Kuwahata, Tsutomu Konno, Hiroki Yamanaka Chem. Lett. 2002, 31, 192–193. (https://doi.org/10.1246/cl.2002.192)

2001年

16	“A Novel and Expedient Synthesis of Optically Active Fluoroalkylated Amino Acids via Palladium-Catalyzed Allylic Rearrangement and Ireland-Claisen Rearrangement” Tsutomu Konno*, Takeshi Daitoh, Takashi Ishihara, Hiroki Yamanaka Tetrahedron: Asymmetry 2001, 12, 2743–2748. (https://doi.org/10.1016/s0957-4166(01)00485-2)
15	“Reaction of β-Trifluoromethyl Vinamidinium Salt with Carbon Nucleophiles” Satoru Shibayama, Tsutomu Konno, Takashi Ishihara, Hiroki Yamanaka* J. Fluorine Chem. 2001, 111, 91–100. (https://doi.org/10.1016/s0022-1139(01)00438-9)
14	“Phosphoric Acid Pseudopeptides Analogous to Glutamyl-γ-glutamate: Synthesis and Coupling to Pteroyl Azides Leads to Potent Inhibitors of Folylpoly-γ-glutamate Synthetase” Nadia Valiaeva, David Bartley, Tsutomu Konno, James K. Coward J. Org. Chem. 2001, 66, 5146–5154. (https://doi.org/10.1021/jo010283t)
13	“Reaction of Trifluoromethylated Ynamines with Halogenating Agents: A Convenient Access to 2-Halo- and 2,2-Dihalo-3,3,3-trifluoropropanamides” Toshiya Mantani, Takashi Ishihara*, Tsutomu Konno, Hiroki Yamanaka J. Fluorine Chem. 2001, 108, 229–237. (https://doi.org/10.1016/s0022-1139(01)00358-x)
12	“Reaction of β-Fluorinated Vinamidinium Salts with Grignard Reagents and Reducing Agents: New Facile and Efficient Route to Fluorinated Allylamines” Hiroki Yamanaka*, Yasumasa Odani, Takashi Ishihara, Tsutomu Konno, John T. Gupton J. Fluorine Chem. 2001, 108, 199–205. (https://doi.org/10.1016/s0022-1139(01)00349-9)
11	“A Convenient Preparation of 3,3,3-Trifluoro-1-propynylamines and Their Lewis Acid Catalyzed Reaction with Carbonyl Compounds Leading to (Z)-α-(Trifluoromethyl)-α,β-unsaturated Amides” Toshiya Mantani, Keisuke Shiomi, Tsutomu Konno, Takashi Ishihara*, Hiroki Yamanaka J. Org. Chem. 2001, 66, 3442–3448. (https://doi.org/10.1021/jo001760v)

〜2000年

10	“Palladium-Catalyzed Coupling Reaction of Fluoroalkylated Propargyl Mesylates with Organozinc Reagents: Novel Synthesis of Optically Active Fluorine-Containing Trisubstituted Allenes” Tsutomu Konno*, Mitsuru Tanikawa, Takashi Ishihara, Hiroki Yamanaka Chem. Lett. 2000, 29, 1360–1361. (https://doi.org/10.1246/cl.2000.1360)
9	“Highly Regio- and Stereo-controlled Pd(0)-Catalyzed Nucleophilic Substitution Reaction for The Synthesis of Optically Active γ-Fluoroalkylated Allylic Alcohols” Tsutomu Konno*, Takashi Ishihara, Hiroki Yamanaka Tetrahedron Lett. 2000, 41, 8467–8472. (https://doi.org/10.1016/s0040-4039(00)01485-4)
8	“The Chemistry of Fluorinated Vinamidinium Salts: Reaction of β-Polyfluoroalkoxy Vinamidinium Salts with Grignard Reagents” Koichiro Kase, Mitsuyoshi Katayama, Tsutomu Konno, Takashi Ishihara, Hiroki Yamanaka* J. Fluorine Chem. 2000, 104, 225–231. (https://doi.org/10.1016/s0022-1139(00)00220-7)
7	“New Synthetic Protocol with Trifluoro-1-propynylamines: An Efficient Access to α-(Trifluoromethyl)-δ-keto Amides via Hetero Diels-Alder Reaction” Toshiya Mantani, Tsutomu Konno, Takashi Ishihara*, Hiroki Yamanaka Chem. Lett. 2000, 29, 666–667. (https://doi.org/10.1246/cl.2000.666)
6	“Chemistry of Fluorinated Enamines. Novel Reaction of Trifluoromethylated Enamine with Grignard Reagents” Hee Moon Park, Tomonori Uegaki, Tsutomu Konno, Takashi Ishihara*, Hiroki Yamanaka Tetrahedron Lett. 1999, 40, 2985–2988. (https://doi.org/10.1016/s0040-4039(99)00399-8)
5	“Stereoselective Synthesis of Trifluoromethylated Compound via Johnson-Claisen and Eschenmoser-Claisen Rearrangement” Tsutomu Konno, Hirofumi Nakano, Tomoya Kitazume* J. Fluorine Chem. 1997, 86, 81–87. (https://doi.org/10.1016/s0022-1139(97)00049-3)
4	“Synthesis of Trifluoromethylated Compounds with Four Consecutive Asymmetric Centers via Sequential [3.3]-Ireland-Claisen Rearrangement and Iodolactonization” Tsutomu Konno, Tomoya Kitazume* Tetrahedron: Asymmetry 1997, 8, 223–230. (https://doi.org/10.1016/s0957-4166(96)00492-2)
3	“Highly Stereoselective Synthesis of Trifluoromethylated Compounds via Ester-Enolate [2,3]-Wittig and [3.3]-Ireland-Claisen Rearrangement” Tsutomu Konno, Hideki Umetani, Tomoya Kitazume* J. Org. Chem. 1997, 62, 137–150. (https://doi.org/10.1021/jo961246i)
2	“Novel Synthesis and Application of g-Difluoromethylated Prop-2-ynylic and Allylic Alcohols” Tsutomu Konno, Tomoya Kitazume* Chem. Commun. 1996, 2227–2228. (https://doi.org/10.1039/cc9960002227)
1	“Synthesis and Application of α-Trifluoromethylated Aldehyde” Tsutomu Konno, Takashi Yamazaki, Tomoya Kitazume* Tetrahedron 1996, 52, 199–208. (https://doi.org/10.1016/s0040-4020(95)00863-4)